We describe the technique of spectropolarimetric observations allowing for the measurements of the Stokes parameters in one of the observational modes of the SCORPIO focal reducer of the 6-m BTA telescope of the SAO RAS. The characteristics of the instrument in the spectropolarimetric mode of observations are given. We present the algorithm of observational data reduction. The capabilities of the SCORPIO spectropolarimetric mode are demonstrated on the examples of observations of various astronomical objects.
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